مروری بر شکل‌شناسی، خواص گرمایی، مکانیکی و الکتریکی نانوکامپوزیت‌های پلی(‌آکریلونیتریل-بوتادی‌ان-استیرن) و نانولوله‌های کربنی

نوع مقاله : تالیفی

نویسندگان

1 پژوهشگاه پلیمر و پتروشیمی ایران

2 عضو هیئت علمی پژوهشگاه پلیمر و پتروشیمی ایران

چکیده

در دو دهه اخیر، مطالعات گسترده‌ای در باره تهیه نانوکامپوزیت‌های پلیمری دارای نانولوله‌های کربنی (CNTs) انجام گرفته است. نتایج به‌دست آمده حاکی از آن است که افزودن مقدار کمی CNTs، موجب افزایش رسانندگی، پایداری گرمایی، بازدارندگی شعله، مدول یانگ، مقاومت به ضربه و اتلاف صوت نانوکامپوزیت‌های پلیمری می‌شود. از چالش‌های مهم در تهیه این نانوکامپوزیت‌ها، چگونگی پراکندگی CNTs و بهبود آن در زمینه پلیمری است. از این رو، روش‌های متفاوتی با کارایی‌‌های مختلف برای دست‌یابی به پراکنش مناسب این نانوذرات در این دسته از مواد ارائه شده است. کارایی نانوکامپوزیت‌های برپایه پلی(‌آکریلونیتریل-بوتادی‌ان-استیرن) (ABS) و CNTs، سبب استفاده از آن‌ها در صنایع مختلف مانند ساخت وسایل الکترونیکی شده است. همچنین در سال‌های اخیر، این مواد نقش مهمی در فرایندهای شکل‌دهی راهبردی مانند ساخت برهم‌افزا ایفا می‌کنند که اهمیت آن‌ها را دوچندان ساخته است. در این مقاله سعی شده است تا اطلاعات به‌نسبت جامعی درباره روش‌های مختلف پراکنش این نانوذرات در زمینه ABS و مطالعه شکل‌شناسی و خواص گرمایی، مکانیکی و الکتریکی نانوکامپوزیت‌های ABS/CNTs ارائه و مقالات و نوشته‌های چاپ شده اخیر مرور شوند.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Morphology, Thermal, Mechanical and Electrical Properties of Poly(acrylonitrile-butadiene-styrene)/Carbon Nanotubes Nanocomposites: A Review

نویسندگان [English]

  • Zahra Soheilpour 1
  • Mohammad Razavi Nouri 1
چکیده [English]

Rapid development in producing carbon nanotubes (CNTs) thermoplastics nanocomposites have been observed in the past two decades. This is because the addition of a small amount of CNTs could increase the thermal stability, flame retardency, conductivity, Young's modulus, impact resistance and sound-proofing of the polymer-based nanocomposites. One of the challenging issues for obtaining the full performance of the nanocomposites is the dispersion of CNTs in a polymeric matrix. There are several methods to achieve a good dispersion of the nanofiller throughout the polymer matrices. It should be noted that the type of method used could play an important role in dispersion of CNTs. Poly(acrylonitrile-butadiene-styrene) (ABS)/CNTs nanocomposites are used in various industries, for instance in manufacturing of the electronic devices. In recent years, there has been an increasing interest in additive manufacturing technologies in which fused deposition modeling (FDM) has the fastest growth rate by using thermoplastics such as ABS as one of the most applicable materials for this processing method. In this paper, our aim is to present some information on ABS/CNTs nanocomposites prepared using different methods and with studies on their morphologies as well as thermal, mechanical and electrical properties by reviewing the recently related published literature.

کلیدواژه‌ها [English]

  • Nanocomposite
  • poly(acrylonitrile-butadiene-styrene)
  • carbon nanotube
  • electrical properties
  • morphology
1.
Modesti M., Besco S., and Lorenzetti A., Handbook of Polymer
Nanocomposites. Processing, Performance and Application,
Springer, Italy, 177-203, 2014.
2.
Ma P.C., Siddiqui N.A., Marom G., and Kim J.K., Dispersion
and Functionalization of Carbon Nanotubes for Polymer-Based Nanocomposites: A Review, Composites Part A, 41, 1345-1367, 2010.
3.
Mousavi L., Nazockdast H., Mohammadi Y., Azizi H., and Saleh Z., The Effect of Mixing Process on Linear Viscoelastic and Electrical Properties of ABS/MWNT Nanocomposites, J. Appl. Polym. Sci., 125, E260–E267, 2012.
4.
Mital G., Dhand V., Rhee K.Y., Park S.J., and Lee W.R., A Review on Carbon Nanotubes and Graphene as Fillers in Reinforced
Polymer Nanocomposites, J. Ind. Eng. Chem., 21, 11-25, 2015.
5.
Mubarak N.M., Abdullah E.C., Jayakumar N.S., and Sahu J.N., An Overview on Methods for the Production of Carbon Nanotubes, J. Ind. Eng. Chem., 25, 1186-1197, 2014.
6.
Journet C. and Bernier P., Production of Carbon Nanotubes, Appl. Phys. A, 67, 1-9, 1998.
7.
Guo T., Nikolaev P., Thess A., Colbert D.T., and Smalley R.E., Catalytic Growth of Single-Walled Nanotubes by Laser Vaporization,
Chem. Phys. Lett., 243, 49-54, 1995.
8.
Al-Saleh M.H., Al-Anid H.K., and Hussain Y.A., CNT/ABS Nanocomposites by Solution Processing: Proper Dispersion and Selective Localization for Low Percolation Threshold, Composites Part A, 46, 53-59, 2013.
9.
Shrivastava N.K., Suin S., Maiti S., and Khatua B.B., An Approach
to Reduce the Percolation Threshold of MWCNT in ABS/MWCNT Nanocomposites Through Selective Distribution
of CNT in ABS Matrix, RSC Adv., 4, 24584-24593, 2014.
10.
Shrivastava N.K., Suin S., Maiti S., and Khatua B.B., Ultralow
Electrical Percolation Threshold in Poly(styrene-co-acrylonitrile)/Carbon Nanotube Nanocomposites, Ind. Eng. Chem. Res., 52, 2858–2868, 2013.
11.
Du J.H., Bai J., and Cheng H.M., The Present Status and Key Problems of Carbon Nanotube Based Polymer Composites, eXPRESS Polym. Lett., 1, 253–273, 2007.
12.
Jyoti J., Basu S., Singh B.P., and Dhakate S.R., Superior Mechanical
and Electrical Properties of Multiwall Carbon Nanotube
Reinforced Acrylonitrile Butadiene Styrene High Performance
Composites, Composites Part B, 83, 58-65, 2015.
13.
Chen J., Du X.C., Zhang W.B., Yang J.H., Zhang N., Huang T., and Wang Y., Synergistic Effect of Carbon Nanotubes and Carbon Black on Electrical Conductivity of PA6/ABS Blend, Compos. Sci. Technol., 81, 1-8, 2013.
14.
Waheed Q., Khan A.N., and Jan R., Investigating the Reinforcement
Effect of Few Layer Graphene and Multi-walled Carbon Nanotubes in Acrylonitrile-Butadiene-Styrene, Polymer,
97, 496-503, 2016.
15.
EI Ghanem H.M., Jawad S.A., Al-Saleh M.H., Hussain Y.A., and Salah W., Effect of DC-Bias on the Dielectric Behavior of CNT/ABS Nanocomposites, Physica B, 418, 41-46, 2013.
16.
Al-Saleh M.H., Al-Saidi B.A., and Al-Zoubi R.M., Experimental
and Theoretical Analysis of the Mechanical and Thermal
Properties of Carbon Nanotube/Acrylonitrile-Styrene-Butadiene Nanocomposites, Polymer, 89, 12-17, 2016.
17.
Lee J.C., Hong Y.S., Nan R.G., Jang M.K., Lee C.S., Ahn S.H., and Kang Y.J., Soundproofing Effect of Nano Particle Reinforced Polymer Composites, J. Mech. Sci. Technol., 22, 1468-1474, 2008.
18.
Pawar S.P., Gandi M., Saraf C., and Bose S., Exceptional Microwave
Absorption in Soft Polymeric Nanocomposites Facilitated
by Engineered Nanostructures, J. Mater. Chem. C, 4, 4954-4966, 2016.
19.
Marcin W., Benedito A., and Gimenez E., Preparation and Characterization of Extruded Nanocomposite Based on Polycarbonate/
Butadiene-Acrylonitrile-Styrene Blend Filled with Multiwalled Carbon Nanotubes, J. Appl. Polym. Sci., 131, 40271-40278, 2014.
20.
Choi Y.S., Xu M., and Chung I.J., Synthesis of Exfoliated Acrylonitrile–
Butadiene–Styrene Copolymer (ABS) Clay Nanocomposites:
Role of Clay as a Colloidal Stabilizer, Polymer, 46, 531–538, 2005.
21.
Petsom A., Roengsumran S., Ariyaphattanakul A., and Sangvanich P., An Oxygen Index Evaluation of Flammability for zinc Hydroxy Stannate and Zinc Stannate as Synergistic Flame Retardants for Acrylonitrile–Butadiene–Styrene Copolymer,
Polym. Degrad. Stab., 80, 17–22, 2003.
22.
Yang S., Castilleja J.R., Barrera E.V., and Lozano K., Thermal Analysis of an Acrylonitrile–Butadiene–Styrene/SWNT Composite,
Polym. Degrad. Stab., 83, 383–388, 2004.
23.
Singh B.K., Kar P., Shrivastava N.K., Banerjee S., and Khatua B.B., Electrical and Mechanical Properties of Acrylonitrile-Butadiene-Styrene/Multiwall Carbon Nanotube Nanocomposites
Prepared by Melt-Blending, J. Appl. Polym. Sci., 124, 3165–3174, 2012.
24.
Chen G.X., Li Y., and Shimizu H., Ultrahigh-Shear Processing for the Preparation of Polymer/Carbon Nanotube Composites, Carbon, 45, 2334–2340, 2007.
25.
Kaiser A.B. and Skákalová V., Electronic Conduction in Polymers,
Carbon Nanotubes and Graphene, Chem. Soc. Rev., 40, 3786-3801, 2011.
26.
Al-Saleh M.H., Influence of Conductive Network Structure on the EMI Shielding and Electrical Percolation of Carbon Nanotube/Polymer Nanocomposites, Synth. Met., 205, 78–84, 2015.
27.
Du F., Fischer J.E., and Winey K.I., Effect of Nanotube Alignment on Percolation Conductivity in Carbon Nanotube/Polymer Composites, Phys. Rev. B: Condens. Matter, 72, 121404(R), 2005.
28.
Al-Saleh M.H. and Sundararaj U., Microstructure, Electrical, and Electromagnetic Interference Shielding Properties of Carbon
Nanotube/Acrylonitrile–Butadiene–Styrene Nanocomposites,
J. Polym. Sci., Part B: Polym. Phys., 50, 1356–1362, 2012.
29.
Sumfleth J., Adroher X.C., and Schulte K., Synergistic Effects in Network Formation and Electrical Properties of Hybrid Epoxy Nanocomposites Containing Multi-Wall Carbon Nanotubes
and Carbon Black, J. Mater. Sci., 44, 3241–3247, 2009.
30.
Shen H., Jiao Q., Zhao Y., Li H., and Sun Z., Electrical Conductivity
and Electromagnetic Interference Shielding Effectiveness
of Multiwalled Carbon Nanotubes Filled ABS Composites,
Adv. Mater. Res., 194-196, 1554-1557, 2011.
31.
Ke K., Pötschke P., Wiegand N., Krause B., and Voit B., Tuning
the Network Structure in Poly(vinylidene fluoride)/Carbon
Nanotube Nanocomposites Using Carbon Black: Towards Improvements of Conductivity and Piezoresistive Sensitivity, ACS Appl. Mater. Interfaces, 22, 14190–14199, 2016.
32.
McNally T., Pötschke P., Halley P., Murphy M., Martin D., Bell S.E.J., Brennan G.P., Bein D., Lemoine P., and Quinn J.P., Polyethylene Multiwalled Carbon Nanotube Composites, Polymer, 46, 8222–8232, 2005.