کاربرد پلیمرهای زیست‌سازگار در طراحی و توسعه نانوژنراتورهای تریبوالکتریک

نوع مقاله : تالیفی

نویسندگان

گروه مهندسی پلیمر، دانشکده مهندسی شیمی، دانشکدگان فنی، دانشگاه تهران، تهران، ایران

10.22063/basparesh.2026.35810.1759

چکیده

کاهش منابع سوخت‌های فسیلی و افزایش چشمگیر زباله‌های الکترونیکی، توسعه فناوری‌های نوین انرژی پایدار را به ضرورتی اجتناب‌ناپذیر تبدیل کرده است. دراین‌میان، نانوژنراتورهای تریبوالکتریک (TENGs) به‌عنوان قطعات کارآمدی برای برداشت انرژی مکانیکی محیطی و تبدیل آن به انرژی الکتریکی، توجه فزاینده‌ای را جلب کرده ‌است. سادگی ساختار، بازده زیاد در بسامد‌های کم، انعطاف‌پذیری و قابلیت تولید در مقیاس بزرگ از مهم‌ترین مزایای این فناوری به‌شمار می‌روند. از راهبردهای مؤثر در بهبود عملکرد و پایداری TENGها، به‌کارگیری پلیمرهای زیست‌سازگار و زیست‌تجزیه‌پذیر است. این مواد به‌دلیل خواص دی‌الکتریک مناسب، انعطاف‌پذیری زیاد و ایمنی زیستی، امکان طراحی قطعات پوشیدنی و کاشتنی پزشکی را فراهم می‌کنند و می‌توانند بدون ایجاد سمیت یا واکنش‌های ناخواسته با بافت‌های زیستی در تماس مستقیم قرار گیرند. افزون‌براین، تخریب‌پذیری طبیعی پس از پایان عمر مفید قطعه، نقش مهمی در کاهش آثار زیست‌محیطی و زباله‌های الکترونیکی ایفا می‌کند. در سال‌های اخیر، استفاده از پلیمرهای طبیعی نظیر سلولوز، کیتوسان و ابریشم و نیز پلیمرهای سنتزی زیست‌سازگار، مانند پلی‌لاکتیک اسید و پلی‌کاپرولاکتون، نتایج امیدبخشی در برداشت انرژی، حسگری و کاربردهای زیست‌پزشکی ارائه داده است. بااین‌حال، چالش‌هایی از جمله دوام محدود، هزینه مواد کارآمد و دشواری تولید در مقیاس صنعتی همچنان پابرجاست. در این مقاله نقش پلیمرهای زیست‌سازگار در طراحی و توسعه TENGها به‌طور جامع مرور شده و ضمن بررسی مزایا و محدودیت‌ها، چشم‌انداز آینده این فناوری در حوزه انرژی پایدار و پزشکی بحث می‌شود.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Application of Biocompatible Polymers in Design and Development of Triboelectric Nanogenerators

نویسندگان [English]

  • Fatemeh Golestani
  • Sara Tarashi
Polymer Engineering Department, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
چکیده [English]

The depletion of fossil fuel resources and the rapid increase in electronic waste have made the development of sustainable energy technologies an inevitable necessity. Meanwhile, triboelectric nanogenerators (TENGs) have attracted growing attention as efficient components for harvesting ambient mechanical energy and converting it into electrical energy. Their simple structure, high efficiency at low frequencies, flexibility, and potential for large-scale manufacturing are among the key advantages of this technology One of the effective strategies in improving the performance and sustainability of TENGs is the use of biocompatible and biodegradable polymers. Due to their suitable dielectric properties, high flexibility, and biological safety, these materials enable the design of wearable and implantable medical devices and can directly contact with biological tissues without causing toxicity or unwanted reactions. In addition, natural degradability after the end of the device lifetime plays an important role in reducing environmental impacts and electronic waste. In recent years, the use of natural polymers such as cellulose, chitosan, and silk, as well as biocompatible synthetic polymers including polylactic acid and polycaprolactone, has demonstrated promising results in energy harvesting, sensing, and biomedical applications. However, challenges such as limited durability, high costs of high-performance materials, and difficulties in large-scale production remain. This review provides a comprehensive overview of the role of biocompatible polymers in the design and development of TENGs, discussing their advantages and limitations while highlighting future perspectives of this technology in sustainable energy and medical applications.

کلیدواژه‌ها [English]

  • triboelectric nanogenerator
  • biocompatible polymer
  • biodegradable
  • sustainable energy
  • wearable device
  1. Strielkowski W., Civín L., Tarkhanova E., Tvaronavičienė M., and Petrenko Y., Renewable Energy in the Sustainable Development of Electrical Power Sector: A Review, Energies, 14, 8240, 2021.
  2. Zhu Q., Sun E., Zhao Z. et al., Biopolymer Materials in Triboelectric Nanogenerators: A Review, Polymers, 16, 1304, 2024.
  3. Zhu G., Peng B., Jing Q., and Wang Z., Triboelectric Nanogenerators as a New Energy Technology: From Fundamentals, Devices, to Applications, Nano Energy, 14, 126-138, 2015.
  4. Wang Y.M., Zeng Q., He L. et al., Fabrication and Application of Biocompatible Nanogenerators, iSci., 24, 102274, 2021.
  5. Chao S., Ouyang H., Jiang D., Fan Y., and Li Z., Triboelectric Nanogenerator Based on Degradable Materials, EcoMat, 3, 12072, 2021.
  6. Arif U., Haider S., Haider A. et al., Biocompatible Polymers and Their Potential Biomedical Applications: A Review, Curr. Pharm. Des., 25, 3608–3619, 2019.
  7. Yum H.Y., Han S.A., Konstantinov K., Kim S.-W., and Kim J.H., Smart Triboelectric Nanogenerators Toward Human-Oriented Technologies: Health Monitoring, Wound Healing, Drug Delivery, Adv. Mater. Technol., 8, 10, 2201500, 2023.
  8. Xiao X., Xiao X., Nashalian A. et al., Triboelectric Nanogenerators for Self-powered Wound Healing, Adv. Healthc. Mater., 10, 20, 2100975, 2021.
  9. Alam S.N., Ghosh A., Shrivastava P. et al., An Introduction to Triboelectric Nanogenerators, Nano Struct. Nano Obj., 34, 100980, 2023.
  10. Wang Z.L., Triboelectric Nanogenerators as New Energy Technology for Self-powered Systems and as Active Mechanical and Chemical Sensors, ACS Nano, 7, 9533–9557, 2013.
  11. Dassanayaka D.G., Alves T.M., Wanasekara N.D., Dharmasena I.G., and Ventura J., Recent Progress in Wearable Triboelectric Nanogenerators, Adv. Funct. Mater., 32, 2205438, 2022.
  12. Pabba D.P., Satthiyaraju M., Ramasdoss A. et al., MXene-Based Nanocomposites for Piezoelectric and Triboelectric Energy Harvesting Applications, Micromachines, 14, 1273, 2023.
  13. Zhang Z., Zhang Q., Zhou Z. et al., High-power Triboelectric Nanogenerators by Using In-Situ Carbon Dispersion Method for Energy Harvesting and Self-powered Wireless Control, Nano Energy, 101, 107561, 2022.
  14. Chen M., Zhou Y., Lang J., Li L., and Zhang Y., Triboelectric Nanogenerator and Artificial Intelligence to Promote Precision Medicine for Cancer, Nano Energy, 92, 106783, 2022.
  15. Sun H., Zhao Y., Jiao S. et al., Environment Tolerant Conductive Nanocomposite Organ Hydrogels as Flexible Strain Sensors and Power Sources for Sustainable Electronics, Adv. Funct. Mater., 31, 2101696, 2021.
  16. Cheng J., Ding W., Zi Y. et al., Triboelectric Micro Plasma Powered by Mechanical Stimuli, Nat. Commun., 9, 3733, 2018.
  17. Hosseini V.S.M., Rashidi S., and Ehsani M.H., Enhancing Sustainable Energy Harvesting with Triboelectric Nanogenerators (TENGs): Advanced Materials and Performance Enhancement Strategies, Renew. Sustain. Energy Rev., 216, 115663, 2025.
  18. Wang C., Shi Q., and Lee C., Advanced Implantable Biomedical Devices Enabled by Triboelectric Nanogenerators, Nanomaterials, 12(8), 1366, 2022.
  19. Zhan F., Wang G., Wu T.T. et al., High Performance Asymmetric Capacitive Mixing with Oppositely Charged Carbon Electrodes for Energy Production from Salinity Differences, J. Mater. Chem. A, 5, 20374-20380, 2017.
  20. Lee JW., Jung S., Lee TW. Et al., High Output Triboelectric Nanogenerator Based on Dual Inductive and Resonance Effects-Controlled Highly Transparent Polyimide for Self-powered Sensor Network Systems, Adv. Energy Mater., 9, 1901987, 2019.
  21. Chen S., Jiang J., Xu F., and Gong S., Crepe Cellulose Paper and Nitrocellulose Membrane-Based Triboelectric Nanogenerators for Energy Harvesting and Self-Powered Human-Machine Interaction, Nano Energy, 61, 69–77, 2019.
  22. Zhang J., Zheng Y., Xu L., and Wang D., Oleic Acid Enhanced Triboelectric Nanogenerator with High Output Performance and Wear Resistance, Nano Energy, 69, 104435, 2020.
  23. Lee J. W. et al., Sustainable Highly Charged C60-Functionalized Polyimide in a Non-Contact Mode Triboelectric Nanogenerator, Energy Environ. Sci., 14, 1004–1015, 2021.
  24. Xia J., Zheng Z., Guo Y., Mechanically and electrically robust, electro-spun PVDF/PMMA blend films for durable triboelectric nanogenerators, Composites Part A, 157, 106914, 2022.
  25. Kang M., Lee D. M., Hyun I., Rubab N., Kim S. H., and Kim S. W., Advances in Bioresorbable Triboelectric Nanogenerators, Chem. Rev., 123, 11559-11618, 2023.
  26. Jiang W., Li H., Liu Z. et al., Fully Bioabsorbable Natural-Materials-Based Triboelectric Nanogenerators, Adv. Mater., 30, 1801895, 2018.
  27. Han Y., Han Y., and Zhang X., Fish Gelatin-Based Triboelectric Nanogenerator for Harvesting Biomechanical Energy and Self-powered Sensing of Human Physiological Signals, ACS Appl. Mater. Interfaces, 12, 16442-16450, 2020.
  28. Wu C., Kima TW., Sung S., Park JH., and Li F, Ultrasoft and Cuttable Paper-Based Triboelectric Nanogenerators for Mechanical Energy Harvesting, Nano Energy, 44, 279-287, 2018.
  29. He X., Zou H., and Geng Z., A Hierarchically Nanostructured Cellulose Fibre-Based Triboelectric Nanogenerator for Self-powered Healthcare Products, Adv. Funct. Mater., 28, 1805540–1805547, 2018.
  30. Pan R., Xuan W., Chen J. et al., Fully Biodegradable Triboelectric Nanogenerators Based on Electrospun Polylactic Acid and Nanostructured Gelatin Films, Nano Energy, 45, 193–202, 2018.
  31. Jao Y.T., Yang P.-K., Chiu C.-M. et al., A Textile-Based Triboelectric Nanogenerator with Humidity-Resistant Output Characteristic and Its Applications in Self-powered Healthcare Sensors, Nano Energy, 50, 513–520, 2018.
  32. Niu Q., Huang L., Lv S., Shao H., Fan S., and Zhang Y., Pulse-Driven Bio-triboelectric Nanogenerator Based on Silk Nanoribbons, Nano Energy, 74, 104837, 2020.
  33. Li Z., Feng H., Zheng Q. et al., Photothermally Tunable Biodegradation of Implantable Triboelectric Nanogenerators for Tissue Repairing, Nano Energy, 54, 390–399, 2018.
  34. Zheng Q., Zou Y., Zhang Y. et al., Biodegradable Triboelectric Nanogenerator as a Life-Time Designed Implantable Power Source, Sci. Adv., 2, 1501478, 2016.
  35. Peng X., Dong K., Ye C. et al., A Breathable, Biodegradable, Antibacterial, and Self-Powered Electronic Skin Based on All-Nanofiber Triboelectric Nanogenerators, Sci. Adv., 6, 9624, 2020.