پیشرفت های اخیر در سنتز الهام‌گرفته از طبیعت چسب های چوب کاملاً زیست‌پایة مقاوم به رطوبت با استفاده از تانیک اسید

نوع مقاله : تالیفی

نویسنده

پژوهشگاه استاندارد

10.22063/basparesh.2025.35696.1739

چکیده

در سال‌های اخیر، توجه به توسعة مواد سازگار با محیط‌زیست، به‌ویژه در صنعت چسب‌، افزایش چشمگیری داشته است. صنعت چوب از عمده­ترین صنایع مصرف­کنندة چسب است. چسب­ های ­چوب سنتزی عمدتاً برپایة رزین­های اوره-فرمالدهید و ملامین-فرمالدهید هستند. آن‌ها طی مراحل ساخت و استفاده، فرمالدهید آزاد می­کنند که برای سلامت انسان بسیار مضر است. در سال­های اخیر، قوانین و دستورکار­های ممنوعیت استفاده از ترکیبات آزادکنندة فرمالدهید در اکثر کشورها وضع شده است. بنابراین، پژوهش‌های گسترده­ ای برای جایگزینی این چسب­ ها انجام شده است. چسب ­های برپایة تانیک اسید (TA) به‌عنوان ترکیبی طبیعی و فراوان، به­ دلیل خواص منحصر به‌فردی چون چسبندگی زیاد، مقاومت به رطوبت، زیست‌سازگاری و خواص ضدمیکروبی، به‌عنوان مادة امیدبخشی در سنتز چسب‌های چوب کاملاً زیست‌پایه مورد توجه قرار گرفته است. در این مقاله، آخرین پیشرفت‌ها در استفاده از تانیک اسید در تولید چسب‌های چوب مقاوم به رطوبت با الهام از ساختارها و سازوکار‌های طبیعی ارائه می‌شود. ابتدا، ویژگی‌های تانیک اسید و نقش آن در بهبود چسبندگی و مقاومت به آب بررسی و سپس روش‌های مختلف اصلاح تانیک اسید و ترکیب اجزا برای دستیابی به چسب‌های کارآمد مرور می‌شود. همچنین، اثر ترکیب تانیک اسید با سایر مواد طبیعی مانند پروتئین‌ها، پلی‌ساکاریدها و نانوذرات برای بهبود خواص مکانیکی و مقاومت به رطوبت بررسی می‌شود. این مطالعه نشان می‌دهد، چسب­ های برپایة تانیک اسید به‌عنوان جایگزین پایدار و کارآمد برای چسب‌های سنتزی برپایة نفت، قابلیت بالقوة زیادی در صنایع چوب، به­ ویژه در محیط­ های مرطوب-زیرآب، دارد.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Recent Advances in Nature-Inspired Synthesis of Fully Bio-Based Moisture-Resistant Wood Adhesivesby Using Tannic Acid

نویسنده [English]

  • Fezzeh Aryanasab
Standard Research Institute (SRI)
چکیده [English]

In recent years, attention to the development of environmentally friendly materials, especially in the adhesive industry, has increased dramatically. The wood industry is one of the largest consumers of adhesives. Synthetic wood adhesives are primarily based on urea-formaldehyde and melamine-formaldehyde resins, which release formaldehyde during manufacturing and use that is highly harmful to human health. In recent years, regulations and guidelines prohibiting the use of formaldehyde-releasing compounds have been established in most countries. Consequently, extensive research has been conducted to replace formaldehyde-based wood adhesives. Tannic acid-based (TA) adhesives, as a natural and abundant compound, have gained attention as a promising material for the synthesis of fully bio-based wood adhesives due to their unique properties, such as high adhesion, moisture resistance, biocompatibility, and antimicrobial properties. In this paper summarizes the latest advances in using tannic acid in producing moisture-resistant wood adhesives, inspired by natural structures and mechanisms is summarized. First, the properties of tannic acid and its role in improving adhesion and water resistance and then various methods of modifying tannic acid and combining components to achieve high-performance adhesives are reviewed. Additionally, the effect of combining tannic acid with other natural materials, such as proteins, polysaccharides, and nanoparticles, to enhance the mechanical properties and moisture resistance is discussed. This study demonstrates that tannic acid-based adhesives have significant potential as a sustainable and efficient alternative to petroleum-based synthetic adhesives in the wood industry, particularly in humid or underwater environments.

کلیدواژه‌ها [English]

  • wood adhesive
  • tannic acid
  • fully-biobased
  • moisture resistance
  • nature-inspired
  1. Yu C., Chen Y., Li R. et al., A Narrative Review: Modification of Bio-Based Wood Adhesive for Performance Improvement, Coatings, 14, 1153-1165, 2024.
  2. Gadhave R.V., Synthesis and Characterization of Starch-Stabilized Polyvinyl Acetate-N-Methylol Acrylamide Polymer-Based Wood Adhesive, J. Indian Acad. Wood Sci., 20, 51-61, 2023.
  3. Xi X., Pizzi A., Lei H. et al., Environmentally Friendly Chitosan Adhesives for Plywood Bonding, Int. J. Adhes. Adhes., 112, 103027, 2022.
  4. Norstrom E., Demircan D., Fogelstrom L. et al., Green Binders for Wood Adhesives, in: Applied Adhesive Bonding in Science and Technology, Ozer H. (Ed.), InTech Open, London, 49-71, 2018.
  5. Arias A., González-Rodríguez S., Vetroni Barros M. et al., Recent Developments in Bio-based Adhesives from Renewable Natural Resources, J. Clean. Prod., 314, 127892, 2021.
  6. Blomquist R.F., Christiansen A.W., Gillespie R.H., and Myers G.E., Adhesives-An Overview. Adhesive Bonding of Wood and Another Structural Materials, Pennsylvania State University, 3-48, 1983.
  7. Lambuth A.L., Hemingway R.W., Conner A.H., and Branham S.J., Adhesives from Renewable Resources. Historical Perspective and Wood Industry Needs, in Adhesives from Renewable Sources, American Chemical Society, Washington, DC, 1-10, 1989.
  8. Chen H., Nair S.S., Chauhan P., and Yan N., Lignin Containing Cellulose Nanofibril Application in pMDI Wood Adhesives for Drastically Improved Gap-filling Properties with Robust Bondline Interfaces, Chem. Eng. J., 360, 393-401, 2019.
  9. Sutiawan J., Syahfitri A., Kusumah S. et al., Influence of Formulation and Hot-Pressing Conditions on the Performance of Bio-Based Molasses Adhesive for Plywood, J. Renew. Mater., 12, 1383-1397, 2024.
  10. Delikhoon M., Fazlzadeh M., Sorooshian A. et al., Characteristics and Health Fffects of Formaldehyde and Acetaldehyde in an Urban Area in Iran, Environ. Pollut., 242, 938-951, 2018.
  11. Ye Q., Han Y., Zhang J. et al., Bio-based Films with Improved Water Resistance Derived from Soy Protein Isolate and Stearic Acid via Bioconjugation, J. Clean. Prod., 214, 125-131, 2019.
  12. Li M., Mao A., Guan Q., and Saiz E., Nature-inspired Adhesive Systems, Chem. Soc. Rev., 53, 8240, 2024.
  13. Cai C., Chen Z., Chen Y. et al., Mechanisms and Applications of Bioinspired Underwater/wet Adhesives, J. Polym. Sci., 59, 2911-2945, 2021.
  14. Narayanan A., Dhinojwala A., and Joy A., Design Principles for Creating Synthetic Underwater Adhesives, Chem. Soc. Rev., 50, 13321-13345, 2021.
  15. Ma C., Pang H., Cai L. et al., Facile Strategy of Mussel-Inspired Polymer as a High-Performance Dry/Wet Adhesive, J. Clean. Prod., 308, 127309, 2021.
  16. Ma Y., Zhang B., Frenkel I. et al., Mussel‐inspired Underwater Adhesives‐from Adhesion Mechanisms to Engineering Applications: A Critical Review, Prog. Adhes. Adhes., 6, 739-59, 2021.
  17. Ghasemi H., Mantazeri S.H., and Hosseinnezhad M., A Review on the Preparation and Application of Tannins as Natural Flame Retardants for Coatings, J. Stud. Color World, 15, 35-46, 2025.
  18. Chen C., Yang H., Yang X., and Ma Q., Tannic Acid: A Crosslinker Leading to Versatile Functional Polymeric Networks: A Review, RSC Adv., 12, 7689, 2022.
  19. Nazari Z., Gharachorloo M., and Elhamirad A.H., Evaluation of the Antioxidative Effects of Black Tea Extracts, J. Food Technol. Nutr., 14, 23-34, 2017.
  20. Guo Z., Xie W., Lu J. et al., Tannic Acid-Based Metal Phenolic Networks for Bio-applications: A Review, J. Mater. Chem. B, 9, 4098-4110, 2021.

21. Hasheminia S.M.,  Ghazalgoo A., Vatankhah A., and Kaviani S.H., The Effect of Mixture of Tannic Acid and Elaeagnus Angustifolia with Psychological Intervention, J. Isfahan Dent. Sch., 19, 197, 2023.

  1. Ma X., Zhou X., Ding J. et al., Hydrogels for Underwater Adhesion: Adhesion Mechanism, Design Strategies and Applications, J. Mater. Chem. A, 10, 11823, 2022.
  2. Oni O.V., Lawrence M.A., Zappi M.E., and Chirdon WM., A Review of Strategies to Enhance the Water Resistance of GreenWood Adhesives Produced from Sustainable Protein Sources, Sustainability, 15, 14779, 2023.
  3. Vineeth S.K., Gadhave R.V., and Gadekar P.T., Nanocellulose Applications in Wood Adhesives- Review, Open J. Polym. Chem., 9, 63-75, 2019.
  4. Bai H., Yu C., Zhu H. et al.,Mussel-Inspired Cellulose-Based Adhesive with Underwater Adhesion Ability, Cellulose, 29, 893-906, 2022.
  5. Zeng Y., Yang W., Xu P., and Ma P., A Water-Resistance Soy Protein-Based Adhesive for Various Substrates Application by Incorporating Tailor-Made Hydrophobic Nanocrystalline Cellulose, Compos. Comm., 32, 101151, 2022.
  6. Maulana M.I., Lubis M.R., Febrianto F. et al., Environmentally Friendly Starch-Based Adhesives for Bonding High-Performance Wood Composites: A Review, Forests, 13, 1614, 2022.
  7. Jeong Y.J., Chathuranga K., Lee J.S. et al., Sustainable Starch-Extracted Amylose-Rich/Tannic Acid Adhesives with Robust Adhesion Properties on Wood Substrates, ACS Sustain. Chem. Eng., 12, 14331-14341, 2024.
  8. Bai M., Cao J., Li J., and Li C., Development of Soybeans Starch Based Tough, Water Resistant and Mildew-Proof Adhesives Through Multiple Cross-Linking Cooperation Strategy, J. Clean. Prod., 321, 129001, 2021.
  9. Schmidt G., Smith K.H., Miles L.J. et al., Tunable Tannic Acid–Zein Adhesives for Bonding Different Substrates, Adv. Sustain. Syst., 6, 2100392, 2022.
  10. Schmidt G., Christ PE., Kertes PE. et al., Underwater Bonding with a Biobased Adhesive from Tannic Acid and Zein Protein, ACS Appl. Mater. Interface., 15, 32863-32874, 2023.
  11. Dhawale P., Gadhave S., and Gadhave R.V., Environmentally Friendly Chitosan-Based Wood/Wood Composite Adhesive: Review, Gr. Sustain. Chem., 13, 237-253, 2023.
  12. Bae H., Shin H.H., and Ryu J.H., Bio-inspired Chitosan/Polyvinyl Alcohol/Tannic Acid Hydrogels as Plant Grafting Wood Adhesives, APL Mater., 12, 111110, 2024.
  13. Qie R., Zajforoushan Moghaddam S., and Thormann E., Fully Biobased Adhesive from Chitosan and Tannic Acid with High Water Resistance, ACS Sustain. Chem. Eng., 12, 4456-4463, 2024.
  14. Bian R., Zhu Y., Lyu Y. et al., Bioinspired ‘Phenol-Amine’ A Cross-linking and Mineral Reinforcement Enable Strong, Tough, and Formaldehyde-Free Tannic Acid-Based Adhesives, J. Clean. Prod., 472, 143490, 2024.
  15. Lambuth A.L., Handbook of Adhesive Technology, Pizzi A. and Mittal K.L. (Eds.), 2nd ed., pp. 457-478, Marcel Dekker, New York, 2003.
  16. Chen S., Shi S.Q., Zhou W., and Li J., Developments in Bio‐Based Soy Protein Adhesives: A Review, Macromol. Mater. Eng., 307, 2200277, 2022.
  17. Ma C., Pang H., Shen Y. et al., Plant Polyphenol-Inspired Crosslinking Strategy Toward High Bonding Strength and Mildew Resistance for Soy Protein Adhesives, Macromol. Mater. Eng., 306, 2100543, 2021.
  18. Sun Y., Pang H., Li Z. et al., Polyphenols Induced in-situ Organic-Inorganic Crosslinking/ Mineralization Strategy for Constructing Eco-Friendly Soy Adhesive with High Waterproof Bonding Strength, Compos. Part B: Eng., 242, 110027, 2022.
  19. Chang Z., Shen Y., Xue J. et al., Fabrication of Strong and Tough Multifunctional Soy Protein Adhesives via Constructing Catechol-iron Ion Fiber-Reinforced Hierarchical Structure Inspired by Mussel Byssus, Ind. Crop. Prod., 202, 116992, 2023.
  20. Chen S., Liu T., Guo Y. et al., Handling-Friendly, Waterproof, and Mildew-Resistant All-Biobased Soybean Protein Adhesives with High-Bonding Performance via Bioinspired Hydrophobic-Enhanced Crosslinking Network, Ind. Crop. Prod., 214, 118583, 2024.
  21. Pan Z., Feng G., Xue Y. et al., A Novel Green Polyurethane Adhesive Based on Castor Oil and Tannic Acid with Excellent Water, Salt, Acid, Alkali and Antibacterial Properties, Ind. Crop. Prod., 204(B), 117325, 2023.
  22. Jiang K., Wu Q., Chen Y. et al., A High-performance Bio-based Adhesive Comprising Soybean Meal, Silk Fibroin, and Tannic Acid Inspired by Marine Organisms, Int. J. Biol. Macromol., 242, 125095, 2023.
  23. Kim E., Jung J.S., Yoon S.G., and Park W.H., Eco-Friendly Silk Fibroin/Tannic Acid Coacervates for Humid and Underwater Wood Adhesives, J. Coll. Interface Sci., 632(A), 151-160, 2023.