مروری بر نقاط کوانتومی کربن و کاربردهای بالقوه آن ها به عنوان پرکننده در نانوکامپوزیت های لاستیکی

نوع مقاله : تالیفی

نویسندگان

1 دانشکده مهندسی شیمی، دانشگاه صنعتی شریف، تهران، ایران

2 استاد، دانشکده مهندسی شیمی و نفت، دانشگاه صنعتی شریف، تهران، ایران

چکیده

نقاط کوانتومی کربن، زیرمجموعه خاصی از نانوذرات کربنی با اندازه حدود 10 nm هستند. از خواص منحصربه فرد آ ن ها می توان به سمیت کم، بی اثری شیمیایی، زیست سازگاری عالی و رفتار درخشایی تنظیم پذیر با اصلاح سطح اشاره کرد. منابع خام متعددی برای تهیه نقاط کوانتومی کربن در طبیعت وجود دارد که هر یک اثر متفاوتی بر خواص این ذرات دارند. تاکنون برای تهیه این ذرات روش های
متعددی ازجمله برسایش لیزری، تابش ریزموج، واکنش گرمابی، اکسایش الکتروشیمیایی، بازروانی و فراصوت دهی به کار گرفته شده اند. نقاط کوانتومی کربن به دلیل اندازه ذرات کوچک دارای خواص فلوئورسان تنظیم پذیر قوی هستند. از این ذرات می توان در کاربردهای متنوع مانند نورکاتالیزگر، حسگر یونی، تصویربرداری زیستی، تشخیص فلزات سنگین، تصفیه برجذبی، ابرخازن، ساخت غشا و تصفیه آلودگی آب بهره برد. در سال های اخیر، پژوهش ها در زمینه استفاده از نقاط کوانتومی کربن در مواد پلیمری، به ویژه مواد کامپوزیتی تقویت شده با این نانوذرات، مورد توجه قرار گرفته اند. این مسئله به دلیل خواص منحصربه فرد نقاط کوانتومی کربن از قبیل تجدیدپذیری، پایداری، خواص مکانیکی زیاد، سبکی و ارزانی آن هاست. هدف از این مقاله، بررسی خواص فیزیکی، شیمیایی و پایداری نقاط کوانتومی کربن و معرفی انواع مواد اولیه، روش های ساخت و کاربردهای آن ها، به ویژه در صنعت لاستیک است. درنهایت، پیشرفت های اخیر در زمینه استفاده از نقاط کوانتومی کربن در محصولات لاستیکی و اثر آنها بر خواص مکانیکی و دینامیکی مرور می شود.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

A Review on Carbon Quantum Dots and Their Potential Applications as Filler in Rubber Nanocomposites

نویسندگان [English]

  • mehdi ghanbari adivi 1
  • akbar shojaei 2
1 Chemical Engineering Faculty، Sharif University of Technology،Tehran، Iran
2 Professor، Faculty of Chemical and Petroleum Engineering، Sharif University of Technology، Tehran، Iran
چکیده [English]

Carbon quantum dots (CQDs) are a special subset of carbon nanoparticles with average dimensions about 10 nm. Their unique properties include low toxicity, chemical inertness, excellent biocompatibility, and tunable luminescence behavior by surface modification. There are several sources for synthesis of CQDs in nature, each of which has different effects on the properties of these particles. So far, several methods have been used to synthesize CQDs including laser ablation, microwave radiation, hydrothermal reaction, electrochemical oxidation, reflux method, and ultrasonication. Due to the small particle size, CQDs have strong tunable fluorescent properties. The usage of these particles has been examined in various fields such as photocatalysis, ion sensor, biological imaging, heavy metal detection, adsorption treatment, supercapacitor, membrane fabrication, and water pollution treatment. Research works on the field of using CQDs in polymer materials, especially CQDs-reinforced composite materials have received attention in recent years. This is due to unique properties of carbon quantum dots such as renewability, stability, high mechanical properties, low weight, and comparatively low cost. This review article is aimed to discuss the physical, chemical and stability properties of CQDs, raw materials and synthesis methods as well as their potential applications in various fields, especially in the rubber industry. Finally, recent developments in the field of using carbon quantum dots in rubber products and their effects on the improvement of mechanical and dynamic properties are reviewed.

کلیدواژه‌ها [English]

  • Carbon quantum dots
  • rubber
  • filler
  • nanocomposite
  • reinforcement

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