کاربرد فرایندهای پلیمرشدن امولسیونی و ادمیسلی در صنعت نساجی

نوع مقاله : تالیفی

نویسندگان

1 پژوهشگاه پلیمر و پتروشیمی ایران

2 پژوهشگاه پلیمر

چکیده

در حین فرایندهای ریسندگی الیاف، تولید نخ، بافندگی پارچه یا رنگرزی آن، عملیات تکمیلی مختلف انجام می‌گیرد تا ارزش افزوده محصول نهایی ارتقا پیدا یابد یا فرایندهای تولید آن با مشکلی مواجه نشود. انجام عملیات تکمیلی باعث می‌شود تا افزون بر ایجاد تغییرات در ساختار فیزیکی و شیمیایی نخ و پارچه، ویژگی­ های نوینی در آن­ها ایجاد شده و در نتیجه دامنه کاربرد این محصولات برای رفع نیاز مشتری گسترده‌تر شود. فرایند پلیمرشدن امولسیونی به­ دلیل مزیت‌هایی چون سادگی فرایند تولید، امکان تولید پلیمرهایی با وزن مولکولی زیاد و مصرف کم انرژی دارای کاربردهای فراوانی در حوزه‌های مختلف، به­ویژه صنایع نساجی است. فرایند پلیمرشدن ادمیسلی نیز ایجاد انواع پوشش‌های پلیمری با ضخامت اندک بر روی انواع سطوح را امکان­ پذیر می ­سازد. بنابراین، به ­دلیل آسانی انجام فرایند پوشش‌دهی، قابلیت زیادی در اصلاح خواص سطحی منسوجات دارد. از فرایندهای پلیمرشدن امولسیونی و ادمیسلی به­ طور گسترده در صنعت نساجی برای انجام عملیات تکمیلی الیاف، نخ و پارچه برای بهبود خواص منسوجات و ایجاد ویژگی ­های جدید در آن­ها استفاده می‌شود. در این مقاله، ابتدا فرایندهای پلیمرشدن امولسیونی و ادمیسلی معرفی می­ شوند. سپس، کاربرد آن­ها در صنعت نساجی شامل عملیات تکمیل منسوجات مانند دافع آب کردن، ضدآتش کردن، رسانای الکتریکی کردن، ضدمیکروب­ سازی، پرتوافکنی فرابنفش، معطرسازی و نیز تولید چسب­ های محلول در آب برای کاربرد در فرایندهای رنگرزی و چاپ پارچه مرور می ­شود.

کلیدواژه‌ها


عنوان مقاله [English]

Application of Emulsion and Admicellar Polymerization Processes in Textile Industry

نویسندگان [English]

  • Ali Akbar Yousefi 1
  • Amirhosein Berendjchi 2
1
2 IPPI
چکیده [English]

During the fiber and/or yarn spinning processes, sizing, weaving or dyeing of the textiles, various finishing treatments are performed on the fibers, yarns or fabrics to increase the added value of the final product or to avoid the technical problems during the textile production. Finishing treatments in addition to making changes in the physical and chemical structure of the yarn and fabric, new characteristics are added to the textiles and as a result, their applications are expanded in order to meet the needs of the customers. Emulsion polymerization has many applications in various fields, especially textile industries, due to its advantages such as simplicity of the production process, possibility of synthesizing polymers with high molecular weight and low energy consumption. Admicellar polymerization also provides the possibility of applying very thin polymeric coatings on various substrates. Therefore, due to the ease of the coating process, it has a great ability to improve the surface properties of textiles. Emulsion and admicellar polymerization processes are widely used in the textile industry for finishing the fibers, yarns and fabrics to improve the properties of textiles. In this article, the emulsion and admicellar polymerization processes is introduced. Then, their applications in the textile industry finishing processes including water and fire repellent, electrical conductivity, antimicrobial, ultraviolet shedding, fragrance textiles as well as the production of water-soluble adhesives for use in fabrics dyeing and printing were reviewed.

کلیدواژه‌ها [English]

  • textiles
  • finishing
  • polymerization
  • emulsion
  • admicelle
  1. Lovell P.A. and Schork F.J., Fundamentals of Emulsion Polymerization, B iomacromolecules, 21, 4396-4441, 2020.
  2. Ahmady A.R., Hosseinzadeh P., Solouk A., Akbari S., Szulc A.M., and Brycki B.E., Cationic Gemini Surfactant Properties, Its Potential as a Promising Bioapplication Candidate, and Strategies for Improving Its Biocompatibility: A Review, Adv. Colloid Interface Sci., 299, 102581, 2022.
  3. Zhu T., Zhou Z., Qu F., Liu B., and van der Bruggen B., Separation Performance of Ultrafiltration During the Treatment of Algae-Laden Water in the Presence of an Anionic Surfactant, Sep. Purif. Technol., 281, 119894, 2022.
  4. Gong L., Yang W., Sun Y., Zhou C., Wu F., and Zeng H., Fabricating Tunable Superhydrophobic Surfaces Enabled by Surface‐Initiated Emulsion Polymerization in Water, Adv. Funct. Mater., 121, 2214947, 2023.
  5. Wu S., Xiong Q., Li X., Chen D., and Liu B., Properties of Thermally Conductive Silicone Rubbers Filled with Admicellar Polymerized Polypyrrole‐Coated Al2O3 Particles, J. Appl. Polym. Sci., 138, 50205, 2021.
  6. Söylemez M.A., and Kemaloğulları B.Ö., Surface Modificationof Magnetic Nanoparticles via Admicellar Polymerization for Selective Removal of Tetracycline from Real Water Samples, New J. Chem., 45, 6415-6423, 2021.
  7. Abdou L.A.W., El-Molla M.M., Hakeim O.A., El-Gammal M.S., and Shamey R., Synthesis of Nanoscale Binders Through Mini Emulsion Polymerization for Textile Pigment Applications, Ind. Eng. Chem. Res., 52, 2195-2200, 2013.
  8. Gao D., Feng J., Ma J., Lü B., Lin J., and Zhang J., Synthesis of Cationic Binder Through Surfactant-free Emulsion Polymerization for Textile Pigment Applications, Prog. Org. Coat., 77, 1834-1840, 2014.
  9. Li S., Lewis J.E., Stewart N.M., Qian L., and Boyter H., Effect of Finishing Methods on Washing Durability of Microencapsulated Aroma Finishing, J. Text. Inst., 99, 177-183, 2008.
  10. Maity J., Kothary P., O’Rear E.A., and Jacob C., Preparation and Comparison of Hydrophobic Cotton Fabric Obtained by Direct Fluorination and Admicellar Polymerization of Fluoromonomers, Ind. Eng. Chem. Res., 49, 6075-6079, 2010.
  11. Mondal S., Pal S., and Maity J., Transparent and Double-Sided

Hydrophobic Functionalization of Cotton Fabric by SurfactantAssisted Admicellar Polymerization of Fluoromonomers, New J. Chem., 42, 6831-6838, 2018.

  1. Mondal S., Pal S., Chaudhuri A., and Maity J., Fabrication of Fluoropolymer-Modified Hydrophobic Functionalization of Cotton Fabric by Admicellar Polymerization, J. Text. Inst., 110, 1747-1754, 2019.
  2. Kim T., Kang H., and Yoon N., Synthesis of Non-fluorinated Paraffinic Water Repellents and Application Properties on Textile Fabrics, Fibers Polym., 18, 285-289, 2017.
  3. Huang P.Y., Chao Y.C., and Liao Y.T., Preparation of Fluoroacrylate Nanocopolymer by Miniemulsion Polymerization Used in Textile Finishing, J. Appl. Polym. Sci., 94, 1466-1472, 2004.
  4. Tragoonwichian S., Kothary P., Siriviriyanun A., Edgar A.O., and Yanumet N., Silicon-Compound Coating for Preparation of Water Repellent Cotton Fabric by Admicellar Polymerization, Colloids Surf. A, 384, 381-387, 2011.
  5. Naz F., Zuber M., Zia K.M., Salman M., Chakraborty J., Nath I., and Verpoort F., Synthesis and Characterization of Chitosan-based Waterborne Polyurethane for Textile Finishes, Carbohydr. Polym., 200, 54-62, 2018.
  6. Ren X., Kou L., Kocer H.B., Worley S.D., Broughton R.M., Tzou Y.M., and Huang T.S., Antimicrobial Modification of Polyester by Admicellar Polymerization, J. Biomed. Mater. Res. B: Appl. Biomater., 89, 475-480, 2009.
  7. Du J., Luo X., Zhang L., Liu Y., Li R., Ren X., and Huang T.S., Emulsion Polymerization of N-halamine Polymer for Antibacterial Polypropylene, Text. Res. J., 86, 1597-1605, 2016.
  8. Zhou J., Wang L., Zha X., and Li X., Synthesis of Ag/Fluorine-Containing Polyacrylate Latex Stabilized by Ag Nanoparticle Hybrid Amphiphilic Random Copolymer Micelles via Pickering Emulsion Polymerization and Its Application on Fabric Finishing, Cellulose, 27, 9123-9134, 2020.
  9. Yan T., Zhang M., Jiang J., and Chen N., Synthesis of DBSADoped Polyaniline by Emulsion Polymerization and PANI/PLA Electrospun Fiber Membrane Conductivity, J. Text. Inst., 110, 274-281, 2019.
  10. Liang G., Zhu L., Xu J., Fang D., Bai Z., and Xu W., Investigations of Poly(pyrrole)-Coated Cotton FabricsPrepared in Blends of Anionic and Cationic Surfactants as Flexible Electrode, Electrochim. Acta, 103, 9-14, 2013.
  11. Yang H.T. and Wang L.J., Preparation of Conductive PPy/Cellulose Composite Fabric by Using Admicellar Polymerization, Adv. Mat. Res., 113, 2030-2034, 2010.
  12. Khajavi R. and Berendjchi A., Improvement in Admicellar Polymerization of Polypyrrole on Cotton Fabric Using Precationization to Achieve High Electrical Conductivity, Adv. Polym. Technol., 36, 230-235, 2017.
  13. Liu C., Liang B., Wang Y., Li Y., and Shi G., Core–Shell Nanocapsules Containing Essential Oil for Textile Application, J. Appl. Polym. Sci., 135, 45695, 2018.
  14. Alay S., Göde F., and Alkan C., Synthesis and Thermal Properties of Poly(n‐butyl acrylate)/n‐Hexadecane Microcapsules Using Different Cross‐linkers and their Application to Textile Fabrics, J. Appl. Polym. Sci., 120, 2821-2829, 2011.
  15. Yusuf M., A Review on Flame Retardant Textile Finishing: Current and Future Trends, Curr. Smart Mater., 3, 99-108, 2018.
  16. Rafikov A.S., Yuldosheva O.M.K., Karimov S.K., Khakimova M.S., Abdusamatova D.O., and Doschanov M.R., Three in One: Sizing, Grafting and FireRetardant Treatment for Producing Fire-resistant Textile Material, J. Ind. Text., 51, 8925S-8946S, 2022.
  17. Nabijon N., Ahmed M.R., Adkham R.A.F.I.K.O.V., and Heng Q., Extraction of Collagen from Cattle Skin and Synthesis of Collagen Based Flame Retardant Composition and Introduction into Cellulosic Textile Material by Graft Copolymerization, Asian J. Chem., 29, 2470-2474, 2017.
  18. Xue C.H., Zhang L., Wei P., and Jia S.T., Fabrication of Superhydrophobic Cotton Textiles with Flame Retardancy, Cellulose, 23, 1471-1480, 2016.
  19. Tragoonwichian S., Edgar A.O., and Yanumet N., Admicellar Polymerization of 2-Hydroxy-4-acryloyloxybenzophenone: The Production of UV-Protective Cotton, Colloids Surf. A, 329, 87-94, 2008.
  20. Xu C., Hu J., Chen Y., Yang Q., Zhang Y., Wang C., and Chen K., Rapid Synthesis of Strawberry Microcapsules via Pickering Emulsion Photo Polymerization for Use in Multifunctional Fabric Coatings, Prog. Org. Coat., 152, 106110, 2021.